The primary reason to care about dissolved organic carbon in surface water owes to the fact that water sources are chlorinated before distribution to the public. It is a common public requirement to have free chlorine in treated potable water. However, when free chlorine is allowed to come into contact with dissolved organic carbon, a number of byproducts are formed. The primary byproducts that drinking water professionals concern themselves with are two classes of chemicals, trihalomethanes (THM) and haloacetic acids (HAA). In laboratory testing, excess quantities of these two classes of chemicals have shown to have carcinogenic effects. Since this was found, in the early 2000’s, regulators have promoted legislation that limits the quantity of THMs or HAAs that can exist in a distributed water.
There are multiple ways that this THM and HAA problem can be attacked. One way, which has become popular, is to switch from straight chlorination (which relies on the germicidal power of free chlorine) to chloramination, where the germicidal property is not free chlorine, but total chlorine, where the weaker but more long-lasting chlorine-ammonia molecule (chloramine) provides the disinfection function in distributed water. The other primary way of addressing THM/HAA concerns is to reduce the quantity of dissolved organic carbon in the finished, treated water, so that few THM/HAA byproducts can be produced by chlorination.